Two mixed-metal hydride clusters, corresponding to x = 3 and 4, were structurally characterized from a set of atomically precise heptanuclear clusters, CuxAg7−x(H){S2P(OiPr)2}6 (x = 1–6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.
Y. Zhong, J. Liao, T. Chiu, Y. Wu, S. Kahlal, J. Saillard and C. W. Liu, Chem. Commun., 2020, 56, 9300 DOI: 10.1039/D0CC03848B
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