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Issue 72, 2020
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Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

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Abstract

A one-dimensional FeII coordination polymer (CP) has been formed which includes the redox-active ligand bis-pyridyltetrathiafulvalene (py2TTF) and a Schiff base-like N2O2 ligand. This CP is both spin crossover (SCO) and redox-active in the solid-state, and chemical oxidation results in SCO modification.

Graphical abstract: Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

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Article information


Submitted
29 May 2020
Accepted
31 Jul 2020
First published
07 Aug 2020

Chem. Commun., 2020,56, 10469-10472
Article type
Communication

Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

L. Zappe, S. Schönfeld, G. Hörner, K. A. Zenere, C. F. Leong, C. J. Kepert, D. M. D'Alessandro, B. Weber and S. M. Neville, Chem. Commun., 2020, 56, 10469
DOI: 10.1039/D0CC03788E

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