Issue 64, 2020
From the journal:

Chemical Communications

DMAP and PivOH-promoted amination/allenization reaction†

Bo-Sheng Zhang, ORCID logo ‡ab   Yuke Li,‡c   Xue-Ya Gou,b   Zhe Zhang,b   Yang An,b   Xin-Gang Wangb  and  Yong-Min Liang ORCID logo *b  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
E-mail: liangym@lzu.edu.cn

c Department of Chemistry and Centre for Scientific Modeling and Computation, Chinese University of Hong Kong, Shatin, Hong Kong, China

Abstract

This report described the first DMAP and PivOH-promoted ortho-C–H amination and ipso-allenization reaction of iodobenzenes realized by Pd/norbornene cooperative catalysis. Based on control experiments and DFT calculations, we speculated that the three ligands have different functions and mechanism paths in the reaction.

Graphical abstract: DMAP and PivOH-promoted amination/allenization reaction

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Article information

DOI
https://doi.org/10.1039/D0CC03749D
Article type
Communication
Submitted
27 May 2020
Accepted
07 Jul 2020
First published
08 Jul 2020

Chem. Commun., 2020,56, 9202-9205

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DMAP and PivOH-promoted amination/allenization reaction

B. Zhang, Y. Li, X. Gou, Z. Zhang, Y. An, X. Wang and Y. Liang, Chem. Commun., 2020, 56, 9202 DOI: 10.1039/D0CC03749D

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