Pb(OF)Cu3(SeO3)2(NO3): a selenite fluoride nitrate with a breathing kagomé lattice

Mengsi Zhang; Zhiying Zhao; Wanwan Zhang; Jinyang Li; Xiaoying Huang; Zhangzhen He

doi:10.1039/D0CC03684F

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Pb(OF)Cu₃(SeO₃)₂(NO₃): a selenite fluoride nitrate with a breathing kagomé lattice†

Mengsi Zhang,^ab Zhiying Zhao,

^a Wanwan Zhang,^ab Jinyang Li,^a Xiaoying Huang

^a and Zhangzhen He

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: hezz@fjirsm.ac.cn, hcz1988@hotmail.com

^b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

The Cu²⁺-based breathing kagomé material Pb(OF)Cu₃(SeO₃)₂(NO₃) with both corner-sharing and edge-sharing has been synthesized. Magnetic measurements suggest ferromagnetic interactions inside the layers and antiferromagnetic interactions between the neighboring layers, leading to an antiferromagnetic ground state with a field-induced spin–flip transition at low temperature.

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Article information

DOI: https://doi.org/10.1039/D0CC03684F
Article type: Communication
Submitted: 24 May 2020
Accepted: 24 Aug 2020
First published: 25 Aug 2020

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Chem. Commun., 2020,56, 11965-11968

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Pb(OF)Cu₃(SeO₃)₂(NO₃): a selenite fluoride nitrate with a breathing kagomé lattice

M. Zhang, Z. Zhao, W. Zhang, J. Li, X. Huang and Z. He, Chem. Commun., 2020, 56, 11965 DOI: 10.1039/D0CC03684F

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Chemical Communications