A fluoride stabilized sulfur-substituted uranyl complex [U(O)(S)F2] was prepared for the first time via oxidation of U(0) by SOF2 in cryogenic matrixes. The electron withdrawing character of F in this neutral complex does not cause the oxidation of the sulfido ligand by U(VI), but increases the strength and covalency of the U–O and U–S bonds.
R. Wei, X. Chen and Y. Gong, Chem. Commun., 2020, 56, 6782 DOI: 10.1039/D0CC03139A
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