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Issue 51, 2020
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Iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines

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Abstract

Herein, a new method of iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines has been developed. By using readily available substrates, 32 examples of functionalized pyrrolines were prepared in moderate to good yields. Notably, examples of reduction and cycloaddition reactions of the obtained product were given as well.

Graphical abstract: Iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines

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Article information


Submitted
17 Apr 2020
Accepted
19 May 2020
First published
19 May 2020

Chem. Commun., 2020,56, 7045-7048
Article type
Communication

Iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines

Y. Zhang, Z. Yin, H. Wang and X. Wu, Chem. Commun., 2020, 56, 7045
DOI: 10.1039/D0CC02784G

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