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Regio- and diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

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Abstract

An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)2/AsPh3 precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.

Graphical abstract: Regio- and diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

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Article information


Submitted
24 Mar 2020
Accepted
21 May 2020
First published
22 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Regio- and diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

J. Ghouilem, R. Franco, P. Retailleau, M. Alami, V. Gandon and S. Messaoudi, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02175J

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