A planar binuclear cobalt(II) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan

Sergey G. Makarov; Sergey Yu. Ketkov; Dieter Wöhrle

doi:10.1039/D0CC01653E

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A planar binuclear cobalt(ii) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan†

Sergey G. Makarov,

*^a Sergey Yu. Ketkov

^a and Dieter Wöhrle*^b

Author affiliations

* Corresponding authors

^a G.A. Razuvaev Institute of Organometallic Chemistry of RAS, Tropinin str. 49, 603950 Nizhniy Novgorod, Russia
E-mail: makar@iomc.ras.ru
Tel: +7-831-4627370

^b Universität Bremen, Institut für Angewandte und Physikalische Chemie, P.O. Box 330440, 28334 Bremen, Germany
E-mail: woehrle@uni-bremen.de
Tel: +49-421-63135

Abstract

This paper reports on a binuclear Co(II)Pc which exhibits a previously unknown extremely high catalytic activity for the oxidation of a thiol to the corresponding disulfide. The high activity is explained by an electronic contact between the two Co centres in the complex.

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Article information

DOI: https://doi.org/10.1039/D0CC01653E
Article type: Communication
Submitted: 03 Mar 2020
Accepted: 13 Apr 2020
First published: 15 Apr 2020

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Chem. Commun., 2020,56, 5653-5656

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A planar binuclear cobalt(II) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan

S. G. Makarov, S. Yu. Ketkov and D. Wöhrle, Chem. Commun., 2020, 56, 5653 DOI: 10.1039/D0CC01653E

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Chemical Communications

A planar binuclear cobalt(ii) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan†

Abstract

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A planar binuclear cobalt(II) phthalocyanine as a highly efficient catalyst for the oxidation of a mercaptan

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