Top-down fabrication of colloidal plasmonic MoO3−x nanocrystals via solution chemistry hydrogenation

Shaopeng Qi; Guoning Liu; Lu Tan; Jinxi Chen; Yongbing Lou; Yixin Zhao

doi:10.1039/D0CC01015D

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Top-down fabrication of colloidal plasmonic MoO_3−x nanocrystals via solution chemistry hydrogenation†

Shaopeng Qi,^a Guoning Liu,^a Lu Tan,^a Jinxi Chen,

^a Yongbing Lou

*^a and Yixin Zhao

*^b

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory for Science and Application of Molecular Ferroelectrics, Jiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Device, Southeast University, Nanjing, China
E-mail: lou@seu.edu.cn

^b School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, China
E-mail: yixin.zhao@sjtu.edu.cn

Abstract

A high-efficiency top-down approach was used to fabricate orthorhombic MoO_3−x nanocrystals through the synergic effect of oleic acid (OA) and oleylamine (OAm), in which OA provided H⁺ ions and OAm contributed free electrons. This investigation might provide new guidance for manipulating the optical properties of metal oxide semiconductors.

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Article information

DOI: https://doi.org/10.1039/D0CC01015D
Article type: Communication
Submitted: 08 Feb 2020
Accepted: 20 Mar 2020
First published: 20 Mar 2020

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Chem. Commun., 2020,56, 4816-4819

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Top-down fabrication of colloidal plasmonic MoO_3−x nanocrystals via solution chemistry hydrogenation

S. Qi, G. Liu, L. Tan, J. Chen, Y. Lou and Y. Zhao, Chem. Commun., 2020, 56, 4816 DOI: 10.1039/D0CC01015D

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Chemical Communications