Sustainable quantum dot chemistry: effects of precursor, solvent, and surface chemistry on the synthesis of Zn3P2 nanocrystals

Abstract

The quest of exploring alternative materials for the replacement of toxic cadmium- and lead-based quantum dots (QDs) is necessary for envisaging a sustainable future but remains highly challenging. Tackling this issue, we present the synthesis of Zn₃P₂ nanocrystals (NCs) of unprecedented quality. New, reactive zinc precursors yield highly crystalline, colloidally stable particles, exhibiting oxide-free surfaces, size tunability and outstanding optical properties relative to previous reports of zinc phosphide QDs.