Issue 1, 2020
From the journal:

Chemical Communications

Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates†

Wen-Xin Fan,a   Ji-Lin Li,a   Wen-Xin Lv,a   Ling Yang,a   Qingjiang Li ORCID logo a  and  Honggen Wang ORCID logo *ab  

* Corresponding authors

a Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou 510006, China
E-mail: wanghg3@mail.sysu.edu.cn

b State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences of Guangxi Normal University, Guilin 541004, China

Abstract

The iodofluorination of alkynyl and alkenyl MIDA (N-methyliminodiacetyl) boronates led to the synthesis of two types of fluorinated organoborons bearing a valuable C–I bond. The B(MIDA) moiety confers exclusive regioselectivity to the reaction, and the products were formed in generally good yields. Preliminary utility of the products was demonstrated.

Graphical abstract: Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

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Article information

DOI
https://doi.org/10.1039/C9CC08386C
Article type
Communication
Submitted
26 Oct 2019
Accepted
25 Nov 2019
First published
26 Nov 2019

Chem. Commun., 2020,56, 82-85

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Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

W. Fan, J. Li, W. Lv, L. Yang, Q. Li and H. Wang, Chem. Commun., 2020, 56, 82 DOI: 10.1039/C9CC08386C

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