We report the activation of nitrogen-containing oxyanions using an oxygen-deficient polyoxovanadate–alkoxide cluster. Reduction of NO21− and NO31− results in near-quantitative oxygen atom transfer to the coordinatively unsaturated VIII ion, and selective formation of NO. These results provide insight into possible mechanisms of oxyanion reduction by polyoxometalates.
B. E. Petel and E. M. Matson, Chem. Commun., 2020, 56, 555 DOI: 10.1039/C9CC08230A
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