Enhancing magnetic hardness by sonication assisted synthesis of heterometallic carbonato spin-glass Na[Ni(H2O)4Ru2(CO3)4]·3H2O

Jing-Yu Li; Yu-Chen Tian; Li-Na Feng; Zi-Qin Zhou; Lin-Lin Wang; Jian-Hui Yang; Bin Liu

doi:10.1039/C9CC07876B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Enhancing magnetic hardness by sonication assisted synthesis of heterometallic carbonato spin-glass Na[Ni(H₂O)₄Ru₂(CO₃)₄]·3H₂O†

Jing-Yu Li,^a Yu-Chen Tian,^a Li-Na Feng,^a Zi-Qin Zhou,^a Lin-Lin Wang,^a Jian-Hui Yang

^a and Bin Liu

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, P. R. China
E-mail: liubin@nwu.edu.cn

Abstract

Control of magnetic performances of molecular magnets is essential but few efforts have been documented. A green and efficient sonication assisted synthesis of a new heterometallic diruthenium(II,III) carbonate, Na[Ni(H₂O)₄Ru₂(CO₃)₄]·3H₂O (1), was carried out by self-assembling in aqueous solution. Compound 1 exhibits spin-glass behavior below ∼5.0 K, and a systematic investigation of the ultrasonic irradiation influence on the powder samples reveals that their coercivity increases from 50 Oe to 743 Oe with the control of ultrasonic power under appropriate conditions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9CC07876B
Article type: Communication
Submitted: 08 Oct 2019
Accepted: 16 Dec 2019
First published: 16 Dec 2019

Download Citation

Chem. Commun., 2020,56, 1369-1372

Permissions

Request permissions

Enhancing magnetic hardness by sonication assisted synthesis of heterometallic carbonato spin-glass Na[Ni(H₂O)₄Ru₂(CO₃)₄]·3H₂O

J. Li, Y. Tian, L. Feng, Z. Zhou, L. Wang, J. Yang and B. Liu, Chem. Commun., 2020, 56, 1369 DOI: 10.1039/C9CC07876B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications