A dynamic microporous magnet exhibiting room-temperature thermal hysteresis, variable magnetic ordering temperatures and highly selective adsorption for CO2

Zhong-Yi Liu; Hong Zhao; Wei-Chao Song; Xiu-Guang Wang; Zheng-Yu Liu; Xiao-Jun Zhao; En-Cui Yang

doi:10.1039/C8TC03356K

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A dynamic microporous magnet exhibiting room-temperature thermal hysteresis, variable magnetic ordering temperatures and highly selective adsorption for CO₂†

Zhong-Yi Liu,

^a Hong Zhao,^a Wei-Chao Song,^a Xiu-Guang Wang,^a Zheng-Yu Liu,^a Xiao-Jun Zhao

*^ab and En-Cui Yang

*^a

Author affiliations

* Corresponding authors

^a College of Chemistry, Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, P. R. China
E-mail: encui_yang@163.com, xiaojun_zhao15@163.com
Fax: +86-22-23766556

^b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China

Abstract

A dynamic microporous magnet shows reversible temperature-tuned single-crystal-to-single-crystal transformations by stepwise losing of coordinated and lattice water molecules, exhibiting an unusually observed room-temperature hysteresis loop, variable magnetic ordering temperatures and high adsorption selectivity for CO₂ over N₂.

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Article information

DOI: https://doi.org/10.1039/C8TC03356K
Article type: Communication
Submitted: 07 Jul 2018
Accepted: 11 Oct 2018
First published: 11 Oct 2018

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J. Mater. Chem. C, 2019,7, 218-222

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A dynamic microporous magnet exhibiting room-temperature thermal hysteresis, variable magnetic ordering temperatures and highly selective adsorption for CO₂

Z. Liu, H. Zhao, W. Song, X. Wang, Z. Liu, X. Zhao and E. Yang, J. Mater. Chem. C, 2019, 7, 218 DOI: 10.1039/C8TC03356K

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Journal of Materials Chemistry C