Significant average ZT enhancement in Cu3SbSe4-based thermoelectric material via softening p–d hybridization

Abstract

As a tellurium- and lead-free compound, Cu₃SbSe₄ is a promising thermoelectric material with relatively high Seebeck coefficient and low thermal conductivity. Here, an effective strategy of weakening p–d hybridization was proposed and demonstrated to enhance the thermoelectric properties for Cu₃SbSe₄via Ag substitution. This strategy performs a multiple role in high thermoelectric performance, boosting both maximum and average ZT: (1) increase the hole concentration due to the weakened Cu–Se bonding, (2) enlarge the energy gap E_g, putting off the bipolar diffusion, (3) increase the density of states effective mass, and (4) reduce the lattice thermal conductivity mainly due to the large strain fluctuations. As a consequence, a peak ZT ∼ 0.9 at 623 K and a high average ZT above 0.5 for the range 298–623 K can be achieved in a Cu_2.85Ag_0.15SbSe₄ sample. This study provides a new strategy of softening p–d hybridization to boost the thermoelectric performance of Cu₃SbSe₄ by the synergistic regulation of charge carrier and phonon transports, which is also a meaningful guidance to achieve high thermoelectric performance in other copper-based chalcogenides.