A CO2-responsive hydrogel film for optical sensing of dissolved CO2

Abstract

CO₂-monitoring plays an important role in medicine, environmental sciences, and food industries. Here, a new CO₂-responsive hydrogel film was fabricated from branched polyethyleneimine (BPEI) and partially oxidized dextran (PO-Dex) via layer-by-layer (LBL) assembly, based on the in situ Schiff base reaction between the two polymers. The swelling behaviours of the films were studied using Fabry–Perot fringes on their reflection spectra. Like ordinary hydrogels, the BPEI/PO-Dex films swell in water. In addition, they swell to a larger degree when CO₂ is introduced, due to the reaction between CO₂ and the amino groups in BPEI. The CO₂-induced swelling can be reported by the shift of the Fabry–Perot fringes on their reflection spectra; therefore, the BPEI/PO-Dex film can be used as an optical sensor for dissolved CO₂. In the new sensor, the BPEI/PO-Dex film acts as a CO₂-sensing material and Fabry–Perot cavity simultaneously. The introduction of ordered structure is no longer required. The response of the sensor to CO₂ is linear and reversible. Unlike other hydrogel-based sensors that suffer from a slow response, the new sensor can respond to CO₂ quickly, making it applicable for real-time, continuous monitoring of CO₂ levels in solution.