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Surface forces generated by the action of electric fields across liquid films

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Abstract

We explore the force generation and surface interactions arising when electric fields are applied across fluid films. Using a surface force balance (SFB) we measure directly the force between two electrodes in crossed-cylinder geometry across dielectric and electrolytic fluids. In the case of dielectric films the field between the electrodes exerts a force which can be well explained using classic expressions and with no fitting parameters. However when the electrodes are separated by a film of electrolyte, an alternating electric field induces a force which diverges substantially from the calculated static response of the electrolyte. The magnitude of the force is larger than predicted, and the interaction can switch from attractive to repulsive. Furthermore, the approach to steady state in electrolyte takes place over 102–103 s which is very slow compared to both the charging and viscous timescales of the system. The non-trivial electrolyte response in AC electric fields, measured here directly, is likely to underlie several recent reports of unexpected and bifurcating forces driving colloids in AC fields. Our measurements suggest ways to control colloidal and soft matter using electric fields, as well as providing a direct measure of the length- and time-scales relevant in AC electrochemical and electrokinetic systems.

Graphical abstract: Surface forces generated by the action of electric fields across liquid films

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Publication details

The article was received on 21 Jan 2019, accepted on 07 Apr 2019 and first published on 25 Apr 2019


Article type: Paper
DOI: 10.1039/C9SM00143C
Soft Matter, 2019, Advance Article

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    Surface forces generated by the action of electric fields across liquid films

    C. S. Perez-Martinez and S. Perkin, Soft Matter, 2019, Advance Article , DOI: 10.1039/C9SM00143C

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