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Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control

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Abstract

Achieving a higher dissymmetry factor is a crucial issue in developing circularly polarized luminescence (CPL) materials. Here, by tailoring the solvent composition and the morphology of the same chiral emissive small molecules (R- or S-SPAn), circularly polarized emission with a boosted dissymmetry factor (two orders) was realized. It was found that by regulating the water fraction in the mixed THF/H2O, we were able to achieve kinetic control over association of chiral emissive R- or S-SPAn into various nanostructures with 0D nanospheres, 2D nanoflakes and 3D stacked nanoflakes. These nanostructures are all CPL active. Remarkably, the dissymmetry factors of the nanostructures were significantly enhanced compared to those of the molecules and further boosted in different morphologies, from ∼10−4 (0D nanospheres) to 10−3 (2D flake) to ∼10−2 (3D nanoflakes). The enlarged glum value could be assigned to a good packing induced strong luminescence of an excimer. This strategy provides an efficient way to fabricate higher dissymmetry factor CPL organic nanomaterials by only changing the supramolecular architectures while using the same chiral small molecules.

Graphical abstract: Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control

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Publication details

The article was received on 01 Apr 2019, accepted on 01 Jun 2019 and first published on 04 Jun 2019


Article type: Edge Article
DOI: 10.1039/C9SC01577A
Chem. Sci., 2019, Advance Article
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    Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control

    K. Ma, W. Chen, T. Jiao, X. Jin, Y. Sang, D. Yang, J. Zhou, M. Liu and P. Duan, Chem. Sci., 2019, Advance Article , DOI: 10.1039/C9SC01577A

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