Facile synthesis of perovskite CeMnO3 nanofibers as an anode material for high performance lithium-ion batteries

Abstract

A facile synthesis of perovskite-type CeMnO₃ nanofibers as a high performance anode material for lithium-ion batteries was demonstrated. The nanofibers were prepared by the electrospinning technique. The characterization of CeMnO₃ nanofibers was carried out by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy. SEM images manifested nanofibers with a diameter of 470 nm having a rough surface with a porous structure. TEM images were consistent with the observations from the SEM images. The electrochemical properties of CeMnO₃ perovskite in lithium-ion batteries were investigated. The CeMnO₃ anode exhibited a discharge capacity of 2159 mA h g⁻¹ with a coulombic efficiency of 93.79%. In addition, a high cycle stability and a capacity of 276 mA h g⁻¹ at the current density of 1000 mA g⁻¹ can be effectively maintained due to the high Li⁺ conductivity in the CeMnO₃ anode. This study could provide an efficient and potential application of perovskite-type CeMnO₃ nanofibers in lithium-ion batteries.