Issue 68, 2019

Nearly spherical CoP nanoparticle/carbon nanosheet hybrids: a high-performance trifunctional electrocatalyst for oxygen reduction and water splitting

Abstract

Developing active multifunctional electrocatalysts composed of earth-abundant and cheap elements is an urgent demand in energy conversion applications. This study presents a facile approach for the scalable synthesis of nanostructured cobalt phosphide embedded in carbon nanosheets (CoP NPs/CNSs). The hybrid structures show highly efficient trifunctional electrocatalytic activities toward the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) under alkaline condition. The catalytic performances, which are remarkably superior to those of the previously reported CoP nanostructures enclosed by single or a few low index facets, can be attributed to the nearly spherical shape of the CoP nanoparticles with many more exposed crystal planes. Density functional theory (DFT) computations are performed to investigate the facet effects of CoP on electrocatalytic activity, and they reveal the relatively low overpotentials of (101) facets towards the OER and the free energy of water dissociation (ΔGH2O) and adsorbed H intermediates (ΔGH*) of (311) toward the HER being close to thermoneutral. This work is expected to inspire the design and fabrication of multifunctional and high-efficiency electrocatalysts by selectively exposing specific crystal planes.

Graphical abstract: Nearly spherical CoP nanoparticle/carbon nanosheet hybrids: a high-performance trifunctional electrocatalyst for oxygen reduction and water splitting

Supplementary files

Article information

Article type
Paper
Submitted
12 Sep 2019
Accepted
17 Nov 2019
First published
04 Dec 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 39951-39957

Nearly spherical CoP nanoparticle/carbon nanosheet hybrids: a high-performance trifunctional electrocatalyst for oxygen reduction and water splitting

W. Zou, K. Dou, Q. Jiang, J. Xiang, C. Kaun and H. Tang, RSC Adv., 2019, 9, 39951 DOI: 10.1039/C9RA07334E

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