Enhanced removal of fluoride by zirconium modified tea waste with extrusion treatment: kinetics and mechanism

Abstract

To improve the adsorption efficiency of tea-based biosorbents for removing fluoride in drinking water, the novel and effective adsorbent was formed by treating tea waste with extrusion technology. In this study, the extrusion technology was applied to the preparation of adsorbents for the first time. A low-priced and more efficient adsorbent was prepared by loading zirconium onto extruded tea waste (EXT-Zr). Extruded tea waste increased the surface pore size, which could provide more loading sites for zirconium. The EXT-Zr effectively removed fluoride from water in a pH range of 3.0–10.0, which is wider than the pH range of zirconium-loaded tea waste (Tea-Zr). The adsorption was fitted by a pseudo-second order kinetic model and the Langmuir adsorption model. The maximum adsorption capacity was 20.56 mg g⁻¹. The EXT-Zr adsorbent was characterized by Scanning electron microscopy (SEM), Energy-Dispersive Spectroscopy (EDS), X-ray diffraction (XRD), a Brunauer–Emmett–Teller (BET) method, Fourier-transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) to prove the mechanism of how EXT-Zr adsorbs fluoride. The results proved that EXT-based adsorbent will be effective for the enhanced removal of fluoride in drinking water.