Issue 53, 2019

5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions

Abstract

Norbornenone (5b), obtained from the reaction of 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer (3) with bromomaleic anhydride (4b), provides an excellent base-triggered source of carbon monoxide for palladium-catalysed carbonylation reactions. Aminocarbonylation, ketoamide synthesis, and Suzuki–Miyaura reactions of aryl iodides carried out in a two-chamber reaction vessel gave good to excellent yields of carbonylated products.

Graphical abstract: 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions

Supplementary files

Article information

Article type
Paper
Submitted
22 Aug 2019
Accepted
20 Sep 2019
First published
30 Sep 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 30736-30740

5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions

C. M. Payne, K. Cho and D. S. Larsen, RSC Adv., 2019, 9, 30736 DOI: 10.1039/C9RA06594F

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