Effects of octamethylcyclotetrasiloxane grafting and in situ silica particle generation on the curing and mechanical properties of a styrene butadiene rubber composite

Abstract

The reinforcement of octamethylcyclotetrasiloxane (D₄) grafted styrene butadiene rubber (SBR-g-D₄) with in situ generated silica was performed using the sol–gel reaction of tetraethoxysilane (TEOS) in latex. The characterization of SBR-g-D₄ and in situ generated silica reinforced SBR-g-D₄ was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The grafting efficiency of the styrene butadiene rubber (SBR) was determined by a gravimetric method. It was found that the constant silicon content and the grafting efficiency of SBR were 1.72% and 0.13 wt% when the weight ratio of D₄ to SBR was 0.20. The effects of the D₄ and in situ generated silica content on the curing characteristics, mechanical properties and morphology of SBR latex were investigated. The mechanical properties of in situ generated silica reinforced SBR-g-D₄ vulcanizates were improved significantly compared to raw SBR vulcanizate when the in situ generated silica content was 18.05%. Compared with silica reinforced SBR-g-D₄, the tensile strength, wet skid resistance and rolling resistance of the in situ generated silica reinforced SBR-g-D₄ were better. This is because of the higher crosslinking degree in the SBR-g-D₄ matrix and the strong chemical bond between SBR-g-D₄ molecular chains and in situ generated silica. Scanning electron microscopy analysis revealed good silica filler dispersion in all the reinforced SBR-g-D₄ vulcanizates.