Removal of refractory organics in dinitrodiazophenol industrial wastewater by an ultraviolet-coupled Fenton process

Abstract

A significant amount of biorefractory organic wastewater is generated during the production of dinitrodiazophenol (DDNP). In this study, ultraviolet light (254 nm) that was coupled with the Fenton (UV-Fenton) process was applied to treat refractory organics in DDNP industrial wastewater. The effects of key parameters (i.e., H₂O₂ dose, Fe²⁺ dosage, and initial pH) on the treatment efficacy for DDNP industrial wastewater by the UV-Fenton process was investigated systematically. Alcohol quenching experiments were carried out to identify reactive oxygen species in the UV-Fenton process. The treatment efficacy and degradation characteristics of refractory organics were studied and compared by using control experiments. Increasing H₂O₂ and Fe²⁺ doses could lead to improved treatment results to a different extent. A more intense reaction and better treatment results were achieved by using the UV-Fenton process at lower pH conditions. Under optimal conditions of H₂O₂ dose = 7.5 mL L⁻¹, Fe²⁺ dosage = 0.05 mM, and initial pH = 5.0, the pseudo-first order constants k for chemical oxygen demand removal and color number removal were 0.18 min⁻¹ and 1.24 min⁻¹, and the chemical oxygen demand and color number removal efficiencies were 74.24% and 99.94%, respectively. The treatment results for the UV-Fenton process were better than other processes under the same conditions, and a significant synergetic effect was observed for the UV-Fenton process. Alcohol quenching experiments indicated that the predominant reactive oxygen species in the UV-Fenton process was the hydroxyl radical (·OH). Because more ·OH was produced, the UV-Fenton process exhibited a much better treatment performance in degrading and destroying organic structures (i.e., benzene rings, –NO₂, and –NN–). Furthermore, the biodegradability indicated by the biological oxygen demand/chemical oxygen demand ratio was improved considerably to 0.48 from 0.054. The good treatment performance by UV-Fenton allowed for a more efficient electrical energy consumption compared with the UV and UV-H₂O₂. This study provides a theoretical reference for DDNP industrial wastewater treatment by using the UV-Fenton process.