Full-color-emitting (CuInS2)ZnS-alloyed core/shell quantum dots with trimethoxysilyl end-capped ligands soluble in an ionic liquid

Abstract

Zinc-copper-indium sulfide (ZCIS)-alloyed quantum dots are emerging as a new family of low toxic I–III–VI semiconductors due to their broad and color-tunable emissions as well as large Stokes shifts. Here, we fabricated a series of ZCIS QDs with tunable PL wavelengths and band-gap energies via a facile strategy by varying the ratio of A1–3 stock (Cu⁺/In³⁺) to the B stock (Zn²⁺) content. The ZnS shell was formed to improve the PL emission efficiency of the core nanoparticles and the PL emission wavelength of the resulting ZCIS/ZnS NCs gradually blue-shifted with an increase in the number of shell layers, resulting in a wide range of emissions from 800 nm to 518 nm that can be tuned by the core compositions or shell layer numbers for ZCIS/ZnS. Finally, the long-chain ligands dodecanethiol/octadecylamine on the quantum dots' surface were efficiently replaced by (3-mercaptopropyl)trimethoxysilane, thus enabling their solubility in an ionic liquid, which was confirmed via GC-MS. It also benefited for the co-dissolution of the polymers and chemical binding with other materials through the reactive silanol group, which provide stable and well-distributed ZCIS/ZnS QDs composites or surface coating by the QDs.