Issue 21, 2019, Issue in Progress

Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones

Abstract

Enantioselective conjugate hydrosilylation of β,β-disubstituted α,β-unsaturated ketones was realized. In the presence of a chiral picolinamide–sulfonate Lewis base catalyst, the reactions provided various chiral ketones bearing a chiral center at the β-position in up to quantitative yields with moderate enantioselectivities.

Graphical abstract: Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones

Supplementary files

Article information

Article type
Paper
Submitted
15 Feb 2019
Accepted
25 Mar 2019
First published
12 Apr 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 11627-11633

Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones

H. Yang, G. Weng, D. Fang, C. Peng, Y. Zhang, X. Zhang and Z. Wang, RSC Adv., 2019, 9, 11627 DOI: 10.1039/C9RA01180C

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