Role of Al-doping with different sites upon the structure and electrochemical performance of spherical LiNi0.5Mn1.5O4 cathode materials for lithium-ion batteries

Abstract

Al-doped spinel LiNi_0.5Mn_1.5O₄ materials with different sites and contents were synthesized by rapid precipitation combined with hydrothermal treatment and calcination. The roles of Al on structural stability and electrochemical performance were studied by utilizing a series of techniques. XRD patterns indicated lower ion diffusion and no impure phased in doped samples. FT-IR and CV results reveal that Al-doped materials possess a Fdm space group with increased disorder and increasing amounts of Mn³⁺. SEM and TEM equipped with EDS were used to characterize the regular morphology accompanied by a complete crystal structure and homogeneous distribution of elements. The Al content at the Ni, Mn, and Ni/Mn sites was optimized to be 5%, 3% and 5% (in total), respectively. The cycling stability was considerably enhanced at an ambient temperature (25 °C) and high temperature (55 °C). A typical Al dual-doped sample at Ni/Mn sites with 5% content delivered a reversible capacity of 113.5 mA h g⁻¹ after 200 cycles at 0.5C. The discharge capacity at 5, 10 and 20C was 127.3, 125.5 and 123.1 mA h g⁻¹, respectively. The discharge capacity remained at 126 mA h g⁻¹ after 50 cycles (55 °C, 0.5C). Subsequent EIS and analytical results of the cycled electrode showed improved structural stability with a lower resistance, stable cathode/electrolyte interface, and reduced dissolution of Mn. These data further demonstrated the feasibility and reliability of preparing high-performance spinel LiNi_0.5Mn_1.5O₄ cathode materials by doping with a suitable amount of Al.