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Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

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Abstract

A bridging (μ2) neutral zwitterionic amidoxime binding mode previously unobserved between amidoximes and uranyl is reported and compared to other uranyl amidoxime complexes. Density functional theory computations show the dinuclear complex exhibits a shallow potential energy surface allowing for facile inclusion of a nonbonding water molecule in the solid-state.

Graphical abstract: Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

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Publication details

The article was received on 19 Feb 2019, accepted on 07 Mar 2019 and first published on 12 Mar 2019


Article type: Research Article
DOI: 10.1039/C9QO00267G
Citation: Org. Chem. Front., 2019, Advance Article

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    Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

    D. A. Decato and O. B. Berryman, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QO00267G

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