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B2pin2-catalyzed oxidative cleavage of a C[double bond, length as m-dash]C double bond with molecular oxygen

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Abstract

B2pin2-catalyzed oxidative cleavage of the C[double bond, length as m-dash]C double bond of an olefin with molecular oxygen as the oxidant and oxygen source has been developed. Various diaryl ketone, diketone, triketone and estrone derivatives were obtained in moderate to excellent yields. The NMP (N-methyl pyrrolidone)-stabilized B-centered radical species was proposed as a possible catalyst.

Graphical abstract: B2pin2-catalyzed oxidative cleavage of a C [[double bond, length as m-dash]] C double bond with molecular oxygen

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Publication details

The article was received on 27 Dec 2018, accepted on 03 Feb 2019 and first published on 06 Feb 2019


Article type: Research Article
DOI: 10.1039/C8QO01412D
Citation: Org. Chem. Front., 2019, Advance Article

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    B2pin2-catalyzed oxidative cleavage of a C[double bond, length as m-dash]C double bond with molecular oxygen

    Z. Cheng, W. Jin and C. Liu, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01412D

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