Issue 23, 2019

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

Abstract

Epoxy-acid vitrimer particles with excellent osmotic and hydrolytic stability were synthesized by miniemulsion polymerization thanks to in situ generation of surfactants from the carboxylic acid reagent and a water-soluble base. The sulfate-free vitrimers formed in this way show greatly reduced creep viscosities.

Graphical abstract: Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

Supplementary files

Article information

Article type
Communication
Submitted
02 May 2019
Accepted
10 May 2019
First published
13 May 2019

Polym. Chem., 2019,10, 3001-3005

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

R. R. Vaidyula, P. Dugas, E. Rawstron, E. Bourgeat-Lami and D. Montarnal, Polym. Chem., 2019, 10, 3001 DOI: 10.1039/C9PY00644C

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