Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO2 and organic vapors

Yanhong Xu; Di Cui; Shuran Zhang; Guangjuan Xu; Zhongmin Su

doi:10.1039/C8PY01476K

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Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO₂ and organic vapors†

Yanhong Xu,

^ab Di Cui,^b Shuran Zhang,^b Guangjuan Xu^b and Zhongmin Su

*^a

Author affiliations

* Corresponding authors

^a Institute of Functional Material Chemistry, Local United Engineering Lab for Power Batteries, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China
E-mail: zmsu@nenu.edu.cn

^b Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, China

Abstract

We present two novel porphyrin (Porp)-based conjugated microporous polymers (CMPs; Porp-TPE-CMP and Porp-Py-CMP), formed via an FeCl₃-catalyzed cross-coupling reaction between pyrrole and aromatic aldehyde. The resultant CMPs exhibited high CO₂ selectivity compared with N₂ and CH₄, and good capacity for organic vapors.

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Article information

DOI: https://doi.org/10.1039/C8PY01476K
Article type: Communication
Submitted: 16 Oct 2018
Accepted: 21 Dec 2018
First published: 10 Jan 2019

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Polym. Chem., 2019,10, 819-822

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Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO₂ and organic vapors

Y. Xu, D. Cui, S. Zhang, G. Xu and Z. Su, Polym. Chem., 2019, 10, 819 DOI: 10.1039/C8PY01476K

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Polymer Chemistry