Issue 34, 2019

Visible-light-mediated difunctionalization of vinylcyclopropanes for the synthesis of 1-sulfonylmethyl-3,4-dihydronaphthalenes

Abstract

An efficient method for visible-light-mediated sulfonylation/arylation of the C–C σ-bond in vinylcyclopropanes with sulfonyl chlorides to synthesize 1-sulfonylmethyl-substituted 3,4-dihydronaphalenes has been developed. A radical-type pathway has been proved in this transformation. This difunctionalization procedure shows a series of advantages, such as the use of commercially and easily available sulfonyl chlorides, mild conditions, and eco-friendly energy.

Graphical abstract: Visible-light-mediated difunctionalization of vinylcyclopropanes for the synthesis of 1-sulfonylmethyl-3,4-dihydronaphthalenes

Supplementary files

Article information

Article type
Paper
Submitted
10 Jun 2019
Accepted
29 Jul 2019
First published
30 Jul 2019

Org. Biomol. Chem., 2019,17, 7918-7926

Visible-light-mediated difunctionalization of vinylcyclopropanes for the synthesis of 1-sulfonylmethyl-3,4-dihydronaphthalenes

Q. Wang, W. Zhang, Q. Zhou, C. Zhou, B. Xiong, K. Tang and Y. Liu, Org. Biomol. Chem., 2019, 17, 7918 DOI: 10.1039/C9OB01321K

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