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Issue 18, 2019
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Palladium catalyzed chemo- and site-selective C–H acetoxylation and hydroxylation of oxobenzoxazine derivatives

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Abstract

An efficient protocol for the introduction of acetoxy and hydroxy functionalities on unactivated aryl sp2 carbons of oxobenzoxazine derivatives via an ortho-C–H activation reaction using a palladium catalyst has been developed for the first time. Interestingly, this intermolecular C–H functionalization reaction takes place in a facile and simple manner with high chemo- and site selectivity.

Graphical abstract: Palladium catalyzed chemo- and site-selective C–H acetoxylation and hydroxylation of oxobenzoxazine derivatives

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Article information


Submitted
19 Mar 2019
Accepted
12 Apr 2019
First published
12 Apr 2019

Org. Biomol. Chem., 2019,17, 4465-4469
Article type
Communication

Palladium catalyzed chemo- and site-selective C–H acetoxylation and hydroxylation of oxobenzoxazine derivatives

M. Bakthadoss, P. Vijay Kumar, R. Kumar and V. Agarwal, Org. Biomol. Chem., 2019, 17, 4465
DOI: 10.1039/C9OB00642G

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