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Issue 4, 2019
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Synthesis of 1,3-disubstituted cyclohexenes from dienylethers via sequential hydrozirconation/deoxygenative cyclisation

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Abstract

Access to 1,3-disubstituted cyclohexenes from zirconocenes containing a latent electrophilic allylic fragment is described. Requiring a specific conformation, 6-endo-trig cyclisation is based on the TMSOTf-mediated generation of a stabilized carbocation.

Graphical abstract: Synthesis of 1,3-disubstituted cyclohexenes from dienylethers via sequential hydrozirconation/deoxygenative cyclisation

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Publication details

The article was received on 23 Nov 2018, accepted on 22 Dec 2018 and first published on 26 Dec 2018


Article type: Communication
DOI: 10.1039/C8OB02925C
Citation: Org. Biomol. Chem., 2019,17, 798-802
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    Synthesis of 1,3-disubstituted cyclohexenes from dienylethers via sequential hydrozirconation/deoxygenative cyclisation

    A. Payet, B. Blondeau, J. Behr and J. Vasse, Org. Biomol. Chem., 2019, 17, 798
    DOI: 10.1039/C8OB02925C

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