We report a high-yielding metal templated Cannizzaro reaction for converting symmetrical aromatic crown ether dialdehydes of various types [dibenzo and bis(meta-phenylene)] and sizes (20–32 atom rings) to acid–alcohol functionalized crown ethers in 70–98% yields.
M. A. Rouser and H. W. Gibson, New J. Chem., 2019, 43, 16801 DOI: 10.1039/C9NJ04679H
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