Issue 23, 2019

Multifunctional Nb–Cu nanostructured materials as potential adsorbents and oxidation catalysts for real wastewater decontamination

Abstract

Herein, we report the preparation of two niobium(V)–copper(II)-based materials using a bifunctional dicopper(II) complex as a template. Material 1 was prepared via the coprecipitation method in the presence of an aqueous solution of the dicopper(II) complex (n-Bu4N)4[Cu2L2] (n-Bu4N+ = tetra-n-butylammonium cation and L = N,N′-2,2′-ethylenediphenylenebis(oxamate)), ammonium niobium(V) oxalate (NH4[NbO(C2O4)2(H2O)2]), and ammonia. Material 2 was obtained via the calcination of 1 at 600 °C. Both hybrid materials were characterized via micro-ATR FT-IR and Raman spectroscopy, XRPD, TEM and SEM microscopy, and Brunauer, Emmett and Teller (BET) surface measurements. The microporous nanostructured niobium(V)–copper(II) complex material 1 exhibited a high surface area (200 m2 g−1); whereas, material 2 consisted of a crystalline mixture of Nb2O5 and CuO phases with a low surface area (40 m2 g−1). The ability of both materials to act as adsorbents and heterogeneous catalysts to remove methylene blue dye from real wastewater was evaluated. Material 1 exhibited a remarkable maximum adsorption capacity according to the Langmuir model compared to that of the niobium-based nanostructured material (qmax = 199.20 mg g−1). Both 1 and 2 were used as heterogeneous catalysts for the removal of methylene blue dye from real wastewater by Fenton-like reaction. In the presence of hydrogen peroxide, 2 removed approximately 89% of the dye from water, while 1 removed 85% of the contaminant.

Graphical abstract: Multifunctional Nb–Cu nanostructured materials as potential adsorbents and oxidation catalysts for real wastewater decontamination

Supplementary files

Article information

Article type
Paper
Submitted
20 Mar 2019
Accepted
09 May 2019
First published
10 May 2019

New J. Chem., 2019,43, 9134-9144

Multifunctional Nb–Cu nanostructured materials as potential adsorbents and oxidation catalysts for real wastewater decontamination

T. T. da Cunha, I. F. Silva, W. D. do Pim, I. Binatti, G. M. do Nascimento, H. O. Stumpf, G. C. Santana, L. C. A. Oliveira and C. L. M. Pereira, New J. Chem., 2019, 43, 9134 DOI: 10.1039/C9NJ01427F

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