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Synthesis of amidoglucals and glucal esters via carbonylative coupling reactions of 2-iodoglucal using Mo(CO)6 as a CO source

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Abstract

The synthesis of amidoglucals and glucal esters in good to high yields using 2-iodo-3,4,6-tri-O-acetyl-D-glucal as a substrate, Mo(CO)6 as a carbon monoxide source and PdCl2 as a catalyst is reported. This procedure shows advantages when compared to other published methodologies, as it is carried out in one pot relying on short reaction times at mild temperatures, under ligand-free conditions and with only one equivalent of Mo(CO)6.

Graphical abstract: Synthesis of amidoglucals and glucal esters via carbonylative coupling reactions of 2-iodoglucal using Mo(CO)6 as a CO source

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Publication details

The article was received on 06 Sep 2018, accepted on 29 Nov 2018 and first published on 06 Dec 2018


Article type: Paper
DOI: 10.1039/C8NJ04540B
Citation: New J. Chem., 2019, Advance Article
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    Synthesis of amidoglucals and glucal esters via carbonylative coupling reactions of 2-iodoglucal using Mo(CO)6 as a CO source

    M. P. Darbem, K. S. Kanno, I. M. de Oliveira, C. H. A. Esteves, D. C. Pimenta and H. A. Stefani, New J. Chem., 2019, Advance Article , DOI: 10.1039/C8NJ04540B

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