Issue 7, 2019

Atomic spectrometry update: review of advances in elemental speciation

Abstract

This is the 11th Atomic Spectrometry Update (ASU) to focus on advances in elemental speciation and covers a period of approximately 12 months from December 2017. This ASU review deals with all aspects of the analytical atomic spectrometry speciation methods developed for: the determination of oxidation states; organometallic compounds; coordination compounds; metal and heteroatom-containing biomolecules, including metalloproteins, proteins, peptides and amino acids; and the use of metal-tagging to facilitate detection via atomic spectrometry. The review does not cover fractionation, which is sometimes termed operationally defined speciation. As with all ASU reviews the focus of the research reviewed includes those methods that incorporate atomic spectrometry as the measurement technique. However, because speciation analysis is inherently focused on the relationship between the metal(loid) atom and the organic moiety it is bound to or incorporated within, atomic spectrometry alone cannot be the sole analytical approach of interest. Therefore, molecular detection techniques are also included where they have provided a complementary approach to speciation analysis. As in previous years, As speciation continues to dominate the current literature with a significant number of publications concerning Hg and Se speciation and ‘biomolecules’, in which category a number of papers covered in the Se section could also belong. The number of elements covered in these updates also continues to rise with the speciation analysis of over 20 elements reported this year.

Graphical abstract: Atomic spectrometry update: review of advances in elemental speciation

Article information

Article type
Atomic Spectrometry Update
Submitted
28 May 2019
First published
25 Jun 2019

J. Anal. At. Spectrom., 2019,34, 1306-1350

Atomic spectrometry update: review of advances in elemental speciation

R. Clough, C. F. Harrington, S. J. Hill, Y. Madrid and J. F. Tyson, J. Anal. At. Spectrom., 2019, 34, 1306 DOI: 10.1039/C9JA90028D

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