Issue 14, 2019
From the journal:

Green Chemistry

Organic aluminum hydrides catalyze nitrile hydroboration†

Wenqing Liu,a   Yi Ding,a   Da Jin,a   Qiumiao Shen,a   Ben Yan,a   Xiaoli Ma ORCID logo *a  and  Zhi Yang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, P. R. China
E-mail: maxiaoli@bit.edu.cn

Abstract

Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

Graphical abstract: Organic aluminum hydrides catalyze nitrile hydroboration

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Article information

DOI
https://doi.org/10.1039/C9GC01659G
Article type
Communication
Submitted
17 May 2019
Accepted
27 Jun 2019
First published
01 Jul 2019

Green Chem., 2019,21, 3812-3815

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Organic aluminum hydrides catalyze nitrile hydroboration

W. Liu, Y. Ding, D. Jin, Q. Shen, B. Yan, X. Ma and Z. Yang, Green Chem., 2019, 21, 3812 DOI: 10.1039/C9GC01659G

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