Issue 39, 2019

Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal–metal bonds

Abstract

The synthesis and structural analyses of pincer-type iridium complexes having gallyl- and indyl-metalloligands were achieved utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal–metal bonds. A BH3-coordinated PInP-Ir dihydride complex was also developed as an equivalent to an iridium dihydride complex, which could be a useful catalyst for synthetic reactions.

Graphical abstract: Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal–metal bonds

Supplementary files

Article information

Article type
Communication
Submitted
24 Aug 2019
Accepted
13 Sep 2019
First published
13 Sep 2019

Dalton Trans., 2019,48, 14606-14610

Author version available

Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal–metal bonds

J. Takaya, M. Hoshino, K. Ueki, N. Saito and N. Iwasawa, Dalton Trans., 2019, 48, 14606 DOI: 10.1039/C9DT03443A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements