Issue 39, 2019

Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

Abstract

Systematic bonding analysis has been carried out for transition metal complexes containing more than one redox-active/non-innocent ligand. These complexes include tetralithio spiroaromatic palladole, dicupra[10]annulene, highly reduced nickel cyclooctadiene complex and tris(dithiolene)vanadium(IV). Our detailed bonding analysis reveals a common inter-ligand delocalisation pattern in these cases.

Graphical abstract: Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

Supplementary files

Article information

Article type
Paper
Submitted
06 Jul 2019
Accepted
06 Sep 2019
First published
09 Sep 2019

Dalton Trans., 2019,48, 14801-14807

Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

H. C. Wan, J. Zhang, C. S. Leung, F. K. Sheong and Z. Lin, Dalton Trans., 2019, 48, 14801 DOI: 10.1039/C9DT02806D

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