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Issue 34, 2019
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Synthesis, structure and magnetic properties of a novel high-nuclearity oxo-carboxylate [ZnxCo13–x4-O)4(O2CPh)18] cluster

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Abstract

The charge-neutral bimetallic Zn(II)/Co(II) tridecanuclear oxocarboxylate cluster [ZnxCo13–x4-O)4(O2CPh)18] (x ≈ 5.6) was synthesized under anaerobic conditions by the controlled hydrolysis of an alkylzinc carboxylate [EtZn(O2CPh)] in the presence of cobalt(II) benzoate Co(O2CPh)2. The composition and molecular structure of the resulting aggregates were solved by a combination of elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction.

Graphical abstract: Synthesis, structure and magnetic properties of a novel high-nuclearity oxo-carboxylate [ZnxCo13–x(μ4-O)4(O2CPh)18] cluster

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Supplementary files

Article information


Submitted
04 Jul 2019
Accepted
06 Aug 2019
First published
07 Aug 2019

Dalton Trans., 2019,48, 12828-12831
Article type
Communication

Synthesis, structure and magnetic properties of a novel high-nuclearity oxo-carboxylate [ZnxCo13–x4-O)4(O2CPh)18] cluster

J. Nawrocki, D. Prochowicz, I. Justyniak, J. van Leusen, A. Kornowicz, P. Kögerler and J. Lewiński, Dalton Trans., 2019, 48, 12828
DOI: 10.1039/C9DT02791B

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