Organophosphorus-B(C6F5)3 adducts: towards new solid-state emitting materials

Elzbieta Regulska; Sonja Christ; Johannes Zimmermann; Frank Rominger; Gerardo Hernandez-Sosa; Carlos Romero-Nieto

doi:10.1039/C9DT02258A

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Organophosphorus-B(C₆F₅)₃ adducts: towards new solid-state emitting materials†

Elzbieta Regulska,

^a Sonja Christ,^a Johannes Zimmermann,^bc Frank Rominger,^a Gerardo Hernandez-Sosa

*^bc and Carlos Romero-Nieto

*^ad

Author affiliations

* Corresponding authors

^a Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
E-mail: carlos.romero.nieto@oci.uni-heidelberg.de

^b Light Technology Institute, Karlsruhe Institute of Technology, Engesserstr. 13, 76131 Karlsruhe, Germany

^c InnovationLab, Speyerer Str. 4, 69115 Heidelberg, Germany

^d Faculty of Pharmacy, University of Castilla-La Mancha, Calle Almansa 14 – Edif. Bioincubadora, 02008, Albacete, Spain

Abstract

The coordination of B(C₆F₅)₃ to materials based on six-membered phosphorus heterocycles via P [double bond, length as m-dash] O bonds tunes their physicochemical properties both in solution and in the solid state, remarkably improving their performances in light-emitting layers.

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Article information

DOI: https://doi.org/10.1039/C9DT02258A
Article type: Communication
Submitted: 28 May 2019
Accepted: 28 Jun 2019
First published: 15 Jul 2019

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Dalton Trans., 2019,48, 12803-12807

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Organophosphorus-B(C₆F₅)₃ adducts: towards new solid-state emitting materials

E. Regulska, S. Christ, J. Zimmermann, F. Rominger, G. Hernandez-Sosa and C. Romero-Nieto, Dalton Trans., 2019, 48, 12803 DOI: 10.1039/C9DT02258A

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Dalton Transactions