A new barium fluorooxoborate BaB5O8F·xH2O with large birefringence and a wide UV transparency window

Chunmei Huang; Guopeng Han; Hao Li; Fangfang Zhang; Zhihua Yang; Shilie Pan

doi:10.1039/C9DT00106A

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A new barium fluorooxoborate BaB₅O₈F·xH₂O with large birefringence and a wide UV transparency window†

Chunmei Huang,‡^ab Guopeng Han,

‡^ab Hao Li,^ab Fangfang Zhang,*^abc Zhihua Yang

^abc and Shilie Pan

*^abc

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: ffzhang@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

^c Fujian Institute of Innovation, Chinese Academy of Sciences, Fuzhou, China

Abstract

A new barium fluorooxoborate, BaB₅O₈F·xH₂O (x ≈ 0.17), with two interesting independent three-dimensional B–O/F frameworks has been synthesized by a solid-state reaction in a closed system. Compared with the lead fluorooxoborate PbB₅O₈F, BaB₅O₈F·xH₂O exhibits a comparable birefringence and a wider UV transparency window.

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Article information

DOI: https://doi.org/10.1039/C9DT00106A
Article type: Communication
Submitted: 08 Jan 2019
Accepted: 25 Apr 2019
First published: 26 Apr 2019

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Dalton Trans., 2019,48, 6714-6717

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A new barium fluorooxoborate BaB₅O₈F·xH₂O with large birefringence and a wide UV transparency window

C. Huang, G. Han, H. Li, F. Zhang, Z. Yang and S. Pan, Dalton Trans., 2019, 48, 6714 DOI: 10.1039/C9DT00106A

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Dalton Transactions