Issue 7, 2019

Mg–Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

Abstract

Two Mg–Mg-bonded compounds were synthesized by using the ligands N,N′-bis(dipp)-phenanthrene-9,10-diimine (L2) and N,N′-bis(dipp)-o-phenylenediamine (H2L3; dipp = 2,6-diisopropylphenyl). These new Mg(I) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.

Graphical abstract: Mg–Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

Supplementary files

Article information

Article type
Communication
Submitted
03 Jan 2019
Accepted
18 Jan 2019
First published
25 Jan 2019

Dalton Trans., 2019,48, 2295-2299

Mg–Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

M. Ma, H. Wang, J. Wang, L. Shen, Y. Zhao, W. Xu, B. Wu and X. Yang, Dalton Trans., 2019, 48, 2295 DOI: 10.1039/C9DT00028C

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