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Issue 3, 2019
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Control over coordination self-assembly of flexible, multidentate ligands by stepwise metal coordination of isopyrazole subunits

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Abstract

Structurally flexible oligoisopyrazole molecules were self-assembled into discrete complexes with structural diversity upon palladium coordination. Structural convergence was controlled by a stoichiometry change to induce stepwise metal coordination of isopyrazole subunits. Three different types of complexes were selectively generated from a diisopyrazole ligand. Furthermore, tetraisopyrazole ligands were quantitatively assembled into a discrete complex in a predictable manner.

Graphical abstract: Control over coordination self-assembly of flexible, multidentate ligands by stepwise metal coordination of isopyrazole subunits

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Publication details

The article was received on 15 Dec 2018, accepted on 17 Dec 2018 and first published on 18 Dec 2018


Article type: Communication
DOI: 10.1039/C8DT04935A
Citation: Dalton Trans., 2019,48, 818-822
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    Control over coordination self-assembly of flexible, multidentate ligands by stepwise metal coordination of isopyrazole subunits

    Y. Ashida, Y. Manabe, S. Yoshioka, T. Yoneda and Y. Inokuma, Dalton Trans., 2019, 48, 818
    DOI: 10.1039/C8DT04935A

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