The c-phosphanylimine L1 was employed for the synthesis of the novel titanaaziridine 1 with an intramolecular phosphine donor side following a reductive complexation route. This coordination mode is new for c-phosphanylimines and compound 1 is the first group 4 complex featuring a c-phosphanylimine ligand.
M. Fischer, H. Steinert, M. Schmidtmann and R. Beckhaus, Dalton Trans., 2019, 48, 1936 DOI: 10.1039/C8DT04918A
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