Issue 22, 2019

Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands

Abstract

Manganese(I) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 °C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

Graphical abstract: Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands

Supplementary files

Article information

Article type
Paper
Submitted
28 Aug 2019
Accepted
13 Oct 2019
First published
17 Oct 2019
This article is Open Access
Creative Commons BY license

Catal. Sci. Technol., 2019,9, 6370-6378

Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(I) complexes bearing triazole ligands

O. Martínez-Ferraté, B. Chatterjee, C. Werlé and W. Leitner, Catal. Sci. Technol., 2019, 9, 6370 DOI: 10.1039/C9CY01738K

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