Issue 32, 2019

Understanding photoelectrochemical kinetics in a model CO2 fixation reaction

Abstract

Kinetic studies of photo- and photoelectro-catalysis fixation of CO2 are rare. Herein, a typical CO2 reduction addition to trans-stilbene is studied. Through Tafel analyses, the reaction rate-determining step (RDS) is identified as the first step of an anion free radical generation from the substrate, and the reaction order is 0.5.

Graphical abstract: Understanding photoelectrochemical kinetics in a model CO2 fixation reaction

Supplementary files

Article information

Article type
Communication
Submitted
24 Jun 2019
Accepted
26 Jul 2019
First published
26 Jul 2019

Phys. Chem. Chem. Phys., 2019,21, 17517-17520

Understanding photoelectrochemical kinetics in a model CO2 fixation reaction

B. Zhong, D. He, R. Chen, T. Gao, Y. Wang, H. Chen, Y. Zhang and D. Wang, Phys. Chem. Chem. Phys., 2019, 21, 17517 DOI: 10.1039/C9CP03541A

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