A zinc(II) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

Donghai Sheng; Ying Zhang; Yang Han; Guang Xu; Qingxiang Song; Yanping Hu; Xiangyun Liu; Dongming Shan; Achao Cheng

doi:10.1039/C9CE00513G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A zinc(ii) metal–organic framework with high affinity for CO₂ based on triazole and tetrazolyl benzene carboxylic acid†

Donghai Sheng,*^a Ying Zhang,

*^a Yang Han,^a Guang Xu,^a Qingxiang Song,^a Yanping Hu,^a Xiangyun Liu,^a Dongming Shan^a and Achao Cheng^a

Author affiliations

* Corresponding authors

^a The State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Changping District, Beijing 102249, P. R. China
E-mail: shengdonghai120@163.com, y.zhang@cup.edu.cn
Tel: +8610 89733200

Abstract

A new metal–organic framework {[Zn₂(Htzba)₂(dmtrz)]·(CH₃)₂NH}_n (1) that has already been solvothermally synthesized exhibits a high CO₂ uptake capacity based on experimental and simulation calculation results. Furthermore, the selectivities to CO₂/CH₄ and CO₂/N₂ are predicted by IAST to be 41.19 and 46.21 at 298 K and 100 kPa, respectively. The superior performance suggests that 1 is a promising candidate for CO₂ separation.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9CE00513G
Article type: Paper
Submitted: 05 Apr 2019
Accepted: 13 May 2019
First published: 14 May 2019

Download Citation

CrystEngComm, 2019,21, 3679-3685

Permissions

Request permissions

A zinc(II) metal–organic framework with high affinity for CO₂ based on triazole and tetrazolyl benzene carboxylic acid

D. Sheng, Y. Zhang, Y. Han, G. Xu, Q. Song, Y. Hu, X. Liu, D. Shan and A. Cheng, CrystEngComm, 2019, 21, 3679 DOI: 10.1039/C9CE00513G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm